I've struggled to get my alignment look nice for quite a time now. After a lot of googling I have finally achieved almost what I want:

Now the problem is the equation numbers (1 and 3 in the example), which are not vertically centered to the equations. Please help me getting them right! MWE:
\documentclass[12pt,a4paper]{article}
\usepackage{mathtools}
\usepackage{amsmath, amsfonts, amssymb, siunitx}
\begin{document}
\nocite{*}
\begin{alignat}{2}
&\phantom{U_{\mathrm{HETKELLINEN}}}&f
&= \frac{1}{T}\notag\\
&\Leftrightarrow
&T &=\frac{1}{f}=\SI{0,001}{\second}\\
%
& &\hat{U}
&= \sqrt{2} \cdot U = \SI{14,1421}{\volt}\\
%
& &U_{\mathrm{HETKELLINEN}}
&= \hat{U} \cdot \sqrt{2 \cdot \pi \cdot f \cdot t}\notag\\
& & &= \SI{14,1421}{\volt} \cdot \sqrt{2 \cdot \pi \cdot \SI{1}{\kilo\hertz} \cdot \SI{0,0011}{\second}}\notag\\
&&&= \SI{8,3125}{\volt}
\end{alignat}
\end{document}
