The \arraybackslash was used on answer table at How to auto adjust my last table column width, and why is there Underfull \vbox badness on this table?
\documentclass[10pt,a5paper,twoside]{memoir}
\usepackage[T1]{fontenc}
\usepackage[utf8]{inputenc}
\usepackage[brazil]{babel}
\usepackage{ragged2e}
\usepackage[showframe,pass]{geometry}
\usepackage{ltablex}
\keepXColumns
\begin{document}
\frenchspacing
\setlength\extrarowheight{2pt}
\begin{tabularx}{\linewidth}{|>{\RaggedRight}p{3cm}|>{\arraybackslash}X|}
\caption{Formatação do texto}
\label{tab:a_table_formatacao_de_texto} \\
\hline
\endfirsthead
\multicolumn{2}{c}{\tablename~\thetable: Formatação do texto (continued)} \\
\hline
\endhead
\hline
\multicolumn{2}{r}{\footnotesize to be continued}
\endfoot
\hline
\endlastfoot
Cor & Branco - \\ \hline
Formato do papel & A5 \\ \hline
Gramatura & 75 \\ \hline
Cabeçalho & 0,7 \\ \hline
Impressão & Frente e verso \\ \hline
Margens & Espelhadas: superior 2, Inferior: 1,5 \\ \hline
Cabeçalho & 0,7 \\ \hline
Rodapé & 0,7 \\ \hline
Paginação & Externa \\ \hline
Alinhamento vertical & Superior \\ \hline
Cabeçalho & 0,7 \\ \hline
Alinhamento do texto & Justificado \\ \hline
Cor & Branco - \\ \hline
Formato do papel & A5 \\ \hline
Cabeçalho & 0,7 \\ \hline
Gramatura & 75 \\ \hline
Impressão & Frente e verso \\ \hline
Margens & Espelhadas: superior 2, Inferior: 1,5 \\ \hline
Rodapé & 0,7 \\ \hline
Paginação & Externa \\ \hline
Alinhamento vertical & Superior \\ \hline
Alinhamento do texto & Justificado \\ \hline
\end{tabularx}
\end{document}
On the question Difference between \\ and \tabularnewline there is some explaining about it:
\arraybackslash: Restore\\for use in array and tabular environment (after\raggedrightetc.).\def\arraybackslash{\let\\\tabularnewline}
Why \\ is broken by \raggedright and these etc other commands?
Reading the line \def\arraybackslash{\let\\\tabularnewline} seems the \\ is being redefined as \tabularnewline, does \raggedright and these etc other commands redefine it as something else, why?
Does I need to put \arraybackslash only on my last table column? What happens if I do not put it or put on/only a middle column or put on every column?


\raggedrightredefines \ to be\@centercr, which is itself different from the regular definition of \ in regular text (which is different from its definition inside atabularenvironment.) You might want to read the documentation for the LaTeX kernel. (texdoc source2ewill bring up the file.) – Alan Munn Aug 22 '17 at 22:23