New Answer:
\documentclass{article}
\usepackage{tikz}
\usetikzlibrary{arrows,shapes,decorations.markings}
\begin{document}
\begin{tikzpicture}[node distance=2cm, auto]
\tikzstyle{decision} = [diamond, text width=5.9em, text centered, draw=black, fill=blue!20, node distance=4cm]
\tikzstyle{startstop} = [rectangle, text width=7em, rounded corners, minimum height=1cm,text centered, draw=black, fill=white!20, node distance=3cm]
\tikzstyle{process} = [rectangle, text width=6em, text centered, draw=black, fill=white!20, node distance=3cm]
\tikzstyle{line} = [draw, -latex']
\centering
\node [startstop] (inizializza) {INIZIALIZZA MICRO};
\node [process, below of=inizializza] (identifica) {LEGGI PORTA DI INGRESSO};
\node [decision, below of=identifica] (decidi) {PULSANTE PREMUTO?};
\node [process, right of=decidi, node distance=4.5cm] (accendi) {ACCENDI LED};
\begin{scope}[thick,decoration={
markings,
mark=at position 0.5 with {\arrow{>}}}]
\draw[->] (inizializza) -- (identifica);
\draw[->] (identifica) -- (decidi);
\draw[->] (decidi) -- node {si} (accendi);
\draw (decidi.south) --([yshift=-1cm]decidi.south);
\draw[postaction={decorate}] ([yshift=-1cm]decidi.south) node[right,yshift=0.5cm]{No}--([yshift=-1cm,xshift=-3cm]decidi.south);
\draw[postaction={decorate}] ([xshift=-3cm,yshift=-1cm]decidi.south)--([xshift=-3cm,yshift=6cm]decidi.center);
\draw ([xshift=-3cm,yshift=6cm]decidi.center)--([yshift=6cm]decidi.center);
\draw (accendi.east) --([xshift=1.2cm]accendi.east);
\draw[postaction={decorate}] ([xshift=1.2cm]accendi.east) --([xshift=1.2cm,yshift=6cm]accendi.east);
\draw([xshift=1.2cm,yshift=6cm]accendi.east)--([yshift=6cm]decidi.center);
\fill[black] ([yshift=6cm]decidi.center) circle (3pt);
\end{scope}
\end{tikzpicture}
\end{document}
Output:

Old answer:
Try like this:
\documentclass{article}
\usepackage{tikz}
\usetikzlibrary{arrows,shapes,decorations.markings}
\begin{document}
\begin{tikzpicture}[node distance=2cm, auto]
\tikzstyle{decision} = [diamond, text width=5.9em, text centered, draw=black, fill=blue!20, node distance=4cm]
\tikzstyle{startstop} = [rectangle, text width=7em, rounded corners, minimum height=1cm,text centered, draw=black, fill=white!20, node distance=3cm]
\tikzstyle{process} = [rectangle, text width=6em, text centered, draw=black, fill=white!20, node distance=3cm]
\tikzstyle{line} = [draw, -latex']
\centering
\node [startstop] (inizializza) {INIZIALIZZA MICRO};
\node [process, below of=inizializza] (identifica) {LEGGI PORTA DI INGRESSO};
\node [decision, below of=identifica] (decidi) {PULSANTE PREMUTO?};
\node [process, right of=decidi, node distance=4.5cm] (accendi) {ACCENDI LED};
\begin{scope}[thick,decoration={
markings,
mark=at position 0.5 with {\arrow{>}}}]
\draw[postaction={decorate}] (inizializza) -- (identifica);
\draw[postaction={decorate}] (identifica) -- (decidi);
\draw[postaction={decorate}] (decidi) -- node {si} (accendi);
\draw[postaction={decorate}] (decidi.west) --([xshift=-3cm]decidi.west);
\draw[postaction={decorate}] ([xshift=-3cm]decidi.west)--([xshift=-3cm,yshift=6cm]decidi.west);
\draw[postaction={decorate}] ([xshift=-3cm,yshift=6cm]decidi.west)--([yshift=6cm]decidi.center);
\draw[postaction={decorate}] (accendi.east) --([xshift=1.2cm]accendi.east);
\draw[postaction={decorate}] ([xshift=1.2cm]accendi.east) --([xshift=1.2cm,yshift=6cm]accendi.east);
\draw[postaction={decorate}]([xshift=1.2cm,yshift=6cm]accendi.east)--([yshift=6cm]decidi.center);
\fill[black] ([yshift=6cm]decidi.center) circle (3pt);
\end{scope}
\end{tikzpicture}
\end{document}
I used this answer: https://tex.stackexchange.com/a/3172/120578 and your code's image result-> Not the original. If you need more help, please be more specific.
PS: I had to break lines in parts to place the arrow on each middle.
Output:
Edit: Added the dot you request in your title.