There are many ways to place horizontal lines or rules around a title. Here are some examples taken from here and here.
documentclass{article}
\usepackage[utf8]{inputenc}
% First command
\makeatletter
\def\myrulefill{\leavevmode\leaders\hrule height .7ex width 1ex depth -0.6ex\hfill\kern\z@}
\makeatother
% Second command
\newcommand{\textbetweenrules}[2][.4pt]{%
\par\vspace{\topsep}
\noindent\makebox[\textwidth]{%
\sbox0{#2}%
\dimen0=.5\dimexpr\ht0+#1\relax
\dimen2=-.5\dimexpr\ht0-#1\relax
\leaders\hrule height \dimen0 depth \dimen2\hfill
~#2
\leaders\hrule height \dimen0 depth \dimen2\hfill
}\par\nopagebreak\vspace{\topsep}
}
\begin{document}
\Large
\noindent\hrulefill ~Education~\hrulefill
\medskip
\noindent\myrulefill ~Education~\myrulefill\par
\medskip
\textbetweenrules{Education}
\end{document}
The first example is with an ordinary \hrule, which lies at the bottom of the row. The second and third use some predefined commandsas specified.
In the command \textbetweenrules{Education} you can modify the rule widh by putting the parameter between brackets. For example \textbetweenrules[3pt]{Education}