Negation of symbols in LaTeX is typically achieved prepending it with \not. For example

\documentclass{article}
\begin{document}
$18 \equiv 0\ (\textrm{mod}\ 9) \not\equiv 2\ (\textrm{mod}\ 9)$
\end{document}
For more elaborate, larger or lengthy symbols, you can use the cancel package. In those instances \not may not provide a sufficiently-centred negation. The centernot package also provides a centred \not for symbols with larger horizontal dimension.
The ≢ character is in Unicode as U+2262, and can be entered directly with unicode-math. The command for it is \nequiv in many packages, including unicode-math, pxfonts, txfonts, newpxmath, newtxmath, stix, stix2, mnsymbol and fdsymbol.
Other symbol-lookup techniques are described in How to look up a symbol or identify a math symbol or character?
\not\equiv? – Alan Munn Jan 30 '12 at 03:07\notnegate the following operation? – David Faux Jan 30 '12 at 03:12\notis defined zero width relation character in TeX so it will always be on top of the following character. – Alan Munn Jan 30 '12 at 03:22