I'm doing a table with 6 columns with 2 rows of headings. There are 3 principal headings and 6 subheadings. All the columns are c type, however, the columns 3 and 4 ar not correctly centralized. Any help?
\documentclass[12pt,a4paper]{article}
\usepackage{multirow}
\usepackage{multicol}
\usepackage{booktabs}
\usepackage[
font=footnotesize,
justification=centering,
figurewithin=section,
tablewithin=section
]{caption}
\usepackage{siunitx}
\usepackage{chemformula}
\begin{document}
\begin{table}[h]
\centering
\footnotesize
\caption{My caption}
\label{my-label}
\begin{tabular}{cccccc}
\toprule
\multicolumn{2}{c}{\textbf{Time (\si{min})}} &%
\multicolumn{2}{c}{\textbf{Water + \ch{CH3COOH} \SI[inter-unit-product=~]{0,15}{\%~v/v}}} &%
\multicolumn{2}{c}{\textbf{Oil}} \\
\midrule
\textbf{Point 1} & \textbf{Point 2} &%
\textbf{Point 1} & \textbf{Point 2} &%
\textbf{Point 1} & \textbf{Point 2} \\
\midrule
0,00 & 0,00 & 100 & 90 & 0 & 10 \\
0,50 & 0,50 & 90 & 70 & 10 & 30 \\
8,50 & 8,00 & 100 & 0 & 0 & 100 \\
13,50 & 8,10 & 100 & 90 & 0 & 10 \\
\bottomrule
\end{tabular}
\end{table}
\end{document}





Water + CH3COOH 0.15% v/vis wider than the combined with of the third and fourth column. You could either split the line into two or have al look at the answers to the following question: Table column widths disproportionate due to multicolumn cell being too long. – leandriis Mar 18 '19 at 18:51