It is not clear, what you like to achieve. I guess that you like to align your math expressions at two points. This you can do with use of the array or with alignat environments:
\documentclass[12pt]{article}
\usepackage{amsmath}
\begin{document}
\begin{alignat*}{3}
0 & < t_n - a & < \delta\\
-\delta & < a - t_m & < 0
\end{alignat*}
\end{document}

Or you like to align them only at one point? For example as follows:
\documentclass[12pt]{article}
\usepackage{amsmath}
\begin{document}
\begin{align*}
0 & < t_n - a < \delta\\
-\delta & < a - t_m < 0
\end{align*}
\end{document}

Note: in align you can have more than one ampersand. However in such cases even ampersands separate columns of math expressions, which are aligned at odd ampersands.
alignenvironment. Do you like to align your math expression at two points? In this case you should look forarrayor foralignatenvironments. – Zarko Nov 18 '19 at 05:25