I expect that 帀 is not in the font bkai. It is not in bsmi or gbsn either.
Instead of using pdflatex and 8-bit fonts, it is easier to use xelatex and Unicode system fonts.

MWE
%!TeX program = XeLaTeX
\documentclass[varwidth,border=6pt]{standalone}
\usepackage{xeCJK}
\setCJKmainfont{Noto Sans CJK SC}
\usepackage[overlap,CJK]{ruby}
\usepackage{setspace}
\usepackage{xpinyin}
% Start Editing Document
\begin{document}
\Large
%\begin{CJK}{UTF8}{bkai}
\begin{spacing}{2}
\ruby{帀}{Za}
\end{spacing}
%\end{CJK}
%\begin{CJK}{UTF8}{bkai}
\begin{spacing}{2}
\ruby{體}{Ti}
\end{spacing}
%\end{CJK}
\end{document}
Edited to add:
Note that CJKutf8 under pdflatex selects missing characters from the specified (unicode) font, so that:
\begin{CJK}{UTF8}{Noto Serif CJK TC}
\begin{spacing}{2}
\ruby{帀}{Za}
\end{spacing}
\end{CJK}
produces

Edit2:
ruby is not really required if you have xpinyin.
\xpinyin*{帀}
produces

with the tone mark.
It works in both xelatex and pdflatex, but in pdflatex you will have to load a nice-looking font for the Latin of the pinyin using \usepackage{...} (see the manual: do texdoc xpinyin).
Sample

MWE
\documentclass{article}%[12pt,varwidth,border=6pt]{standalone}
\usepackage{xcolor}
\pagecolor{red!3}
\usepackage{fontspec}
\newfontface\ffa{BabelStone Han}[Colour=blue]
\newfontface\ffb{CloudSongDaGBK}
\newfontface\ffc{\detokenize{DFKai-SB}}
\newfontface\ffd{GenEi Koburi Mincho TTF}
\newfontface\ffe{Heiti TC}
\newfontface\fff{IPAexMincho}
\newfontface\ffg{KaiTi}
\newfontface\ffh{Kochi Mincho}
\newfontface\ffi{KouzanBrushFont}
\newfontface\fga{MingLiU}
\newfontface\fgb{NemukeMedium}
\newfontface\fgc{Noto Serif JP}
\newfontface\fgd{Noto Serif JP Black}
\newfontface\fge{Noto Serif JP ExtraLight}
\newfontface\fgf{SentyTang}
\newfontface\fgg{SentyWen}
\newfontface\fgh{Source Han Serif}
\newfontface\fgi{Togoshi Mincho}
\setmainfont{Noto Serif}
\newcommand\mfsize{\huge}
\newcommand\theegsym{帀}
\begin{document}
\section*{Sampling {\mfsize\ffa \theegsym }}
\vspace{24pt}
\begin{tabular}{rccl}
BabelStone Han & \mfsize\ffa \theegsym & \mfsize \fga \theegsym &MingLiU \\
\ &\ & \ & \ \\
CloudSongDaGBK & \mfsize\ffb \theegsym & \mfsize \fgb \theegsym &NemukeMedium \\
\ &\ & \ & \ \\
DFKai-SB & \mfsize\ffc \theegsym & \mfsize \fgc \theegsym &Noto Serif JP \\
\ &\ & \ & \ \\
GenEi Koburi Mincho TTF & \mfsize\ffd \theegsym & \mfsize \fgd \theegsym &Noto Serif JP Black \\
\ &\ & \ & \ \\
Heiti TC & \mfsize\ffe \theegsym & \mfsize \fge \theegsym &Noto Serif JP ExtraLight \\
\ &\ & \ & \ \\
IPAexMincho & \mfsize\fff \theegsym & \mfsize \fgf \theegsym &SentyTang \\
\ &\ & \ & \ \\
KaiTi & \mfsize\ffg \theegsym & \mfsize \fgg \theegsym &SentyWen \\
\ &\ & \ & \ \\
Kochi Mincho & \mfsize\ffh \theegsym & \mfsize \fgh \theegsym &Source Han Serif \\
\ &\ & \ & \ \\
KouzanBrushFont & \mfsize\ffi \theegsym & \mfsize \fgi \theegsym &Togoshi Mincho \\
\end{tabular}
\end{document}