I haven't found an answer that quite fits my situation. I need to link two rectangles, with a curved arrow, passing through the bottom right of a third rectangle, avoiding the text.
I'm using a university-specific document type, so hopefully the below MWE is okay using a normal document style.
\documentclass[a4paper,10pt]{article}
\usepackage[english]{babel}
\usepackage{amsmath,amsthm}
\usepackage{amsfonts}
\usepackage[a4paper,layout=a4paper,
bindingoffset=4cm,left=0cm,right=2cm,
head=2.5cm, bmargin=2cm]{geometry}
\usepackage{microtype}
\usepackage{verbatim}
\usepackage{graphicx}
\usepackage{url}
\usepackage[round]{natbib}
\usepackage{listings}
\usepackage{booktabs}
\usepackage{multirow}
\RequirePackage[l2tabu, orthodox]{nag}
\usepackage{tikz}
\usetikzlibrary{arrows, shapes, chains, fit, backgrounds, calc, decorations.pathreplacing, matrix}
\usepackage{hyperref}
\usepackage{cleveref}
\usepackage[flushleft]{threeparttable}
\usepackage[inline, shortlabels]{enumitem}
\usepackage{tikzlings}
\begin{document}
\begin{figure}[htbp]
\centering
\begin{tikzpicture}[every node/.style=draw, align=center, arrow/.style={thick, -stealth}]
\node[rectangle, fill=white] (PSRW) {One \\ two three \\ four five \\ six};
\node [right, single arrow, inner sep = 10pt, minimum height=1cm, rotate=-45, above left = of PSRW, xshift=1cm, yshift=-.3cm] (NW) {};
\cat[scale=0.6, above right = of PSRW, xshift=10cm, yshift=0cm] (ACat) {};
\mouse[scale=0.5, above right = of PSRW, xshift=13.5cm, yshift=0cm] (AMouse) {};
\node[draw=none, text width=2cm, above right = of PSRW, xshift = 6cm, yshift=-2.5cm] (Imp) {Seven \\ Eight \\ Nine \\ Ten \\ Eleven};
\node[draw=none, text width=2.5cm, below = 3cm of PSRW] (SC) {Twelve \\ Thirteen};
% lines here omitted for brevity
\node[draw=none, text width=1cm, above right = of SC, xshift=1cm, yshift=-.8cm] (TI) {Twelve, \\ thirteen};
\end{tikzpicture}
\caption{Horrible part diagram of hand drawn one}
\label{fig:ThisDiagramIsDrivingMeToDrink}
\end{figure}
\end{document}
The problem is that I need to draw an arrow that goes from the left of the mice, through the bottom right of the PSRW rectangle, and attaches to the north west of the TI box. I would like to use a coordinate system relative to the internal bottom right of the PRSW box. I think that perhaps my supervisors won't like my little images, so that detail there may shift and I don't want to rewrite a bunch of coordinates to deal with any shifting.
I tried:
\draw[arrow] ([xshift=-3cm]Imp.west) to [bend right, looseness=2] (TI.west);
but it doesn't pass through the PSRW box:
I've seen answers based on relative coordinates to the underlying geometry, but none based on relative coordinates to polygons that may shift position.
Perhaps the closest answer I have seen is for the opposite problem so that the curved lines are outside the polygons. The other answers tend to be like this one, which are linking two points directly with a curve.
I can't show the actual (handwritten) diagram that I am trying to replicate due to academic paywall. But if any of you have access to Peter Checkland's work on soft systems methodology, I'm trying to replicate his two-stream diagram using Tikz.
Because of the complexity of the diagram, and my ongoing need to adjust parts of it to fit on the page, I have to place the polygons before I place the arrows.

\draw[thick,-stealth] plot[smooth] coordinates {([yshift=3mm,xshift=-1mm]tikzlings.south west) ([xshift=-1mm,yshift=1mm]PSRW.south east) (TI.north west)};(but now this makes the impression that we cats cut the corners. ;-) – Jan 15 '20 at 09:26