If you want to emulate the “double asterisk” ** used for exponentiation, then
\mathbin{{*}{*}}
is what you need.
The asterisk * by itself produces a Bin atom, without needing \mathbin around it. However two Bin atoms in a row don't make a single Bin atom, because a Bin requires operands around it. Thus the second * would be made into an ordinary symbol.
However, you can make any subformula into a Bin atom by typing it as the argument to \mathbin. By rule, no spacing would be used between the two asterisks with \mathbin{**} (the first would be turned into a unary symbol, just like in -1, and the second into an ordinary, because of the rule above). However, it's better to be more careful and type
\mathbin{{*}{*}}
(the braces hide the nature of * turning it into an ordinary), because the output of
\mathbin{***}
might surprise you. To the contrary, \mathbin{{*}{*}{*}} would not have the problem.
\rm, use\mathrminstead. – Vincent Jan 18 '20 at 23:22\mathbin{...}will give...the spacing rules that + has. – David Carlisle Jan 19 '20 at 00:08