This code does not compile with my tectonic latex compiler. On overleaf it compiles, but it complains about same error with message it fixed it with replacing # with ##. I don't know latex very well but this seems like bug to me.
\documentclass{article}
\usepackage[nogroupskip]{glossaries-extra}
\newglossaryentry{psi}{name=\ensuremath\overleftarrow f, description={left arrow}}
\begin{document}
\printunsrtglossary
\end{document}