You look in the file mathabx.dcl for \leftleftharpoons and \rightrightharpoons to find
\DeclareMathSymbol{\leftleftharpoons} {3}{mathb}{"D8}
\DeclareMathSymbol{\rightrightharpoons} {3}{mathb}{"D9}
Now you know that you need the font called mathb, which you find in mathabx.sty
\DeclareFontFamily{U}{mathb}{\hyphenchar\font45}
\DeclareFontShape{U}{mathb}{m}{n}{
<5> <6> <7> <8> <9> <10> gen * mathb
<10.95> mathb10 <12> <14.4> <17.28> <20.74> <24.88> mathb12
}{}
\DeclareSymbolFont{mathb}{U}{mathb}{m}{n}
\DeclareFontSubstitution{U}{mathb}{m}{n}
I suggest to make the fonts fully scalable at all sizes, so the complete code becomes
\DeclareFontFamily{U}{mathb}{}
\DeclareFontShape{U}{mathb}{m}{n}{
<-5.5> mathb5
<5.5-6.5> mathb6
<6.5-7.5> mathb7
<7.5-8.5> mathb8
<8.5-9.5> mathb9
<9.5-11> mathb10
<11-> mathb12
}{}
\DeclareSymbolFont{mathb}{U}{mathb}{m}{n}
\DeclareFontSubstitution{U}{mathb}{m}{n}
\DeclareMathSymbol{\leftleftharpoons} {\mathrel}{mathb}{"D8}
\DeclareMathSymbol{\rightrightharpoons} {\mathrel}{mathb}{"D9}
(the \hyphenchar declaration is useless).
I changed {3} into \mathrel that's clearer about the role of the symbols (however the two styles are equivalent).
\DeclareMathSymbol{\leftleftharpoons}{\mathrel}{mathb}{"D8} \DeclareMathSymbol{\rightrightharpoon}{\mathrel}{mathb}{"D9}– Bernard Feb 28 '21 at 11:52mathbin the documentation, p. 19 (it's not as simple for all font packages…). – Bernard Feb 28 '21 at 12:30mathrel, mathbin,…) and the font it belongs to (matha,mathb,mathx), then see from the tables their hexadecimal code (indicated with the prefix"). The rest of the code is unchanged, as far as I remember, at least for non-delimiters. – Bernard Feb 28 '21 at 12:47mathbbymathaand this will do the job. Thanks for all. – projetmbc Feb 28 '21 at 13:44fonttableto print out the font map, which tells you that information. – Steven B. Segletes Feb 28 '21 at 18:04