What you are seeing are the sidebearings of the character.
Try this code (needs lualatex) for turning the switch \dropsidebearings on and off. Courtesy of Marcel Krüger.
See Dot won't properly align with text and links in it.


% !TeX TS-program = lualatex
\documentclass[12pt, a4paper]{article}
\RequirePackage{showframe} % margin line
\renewcommand\ShowFrameLinethickness{0.1pt}
\renewcommand\ShowFrameColor{\color{red}}
\RequirePackage{luacode}
\newcount\dropsidebearings
\begin{luacode*}
------------------------drop_sidebearing------------------------
--https://tex.stackexchange.com/questions/427068/sidebearings-and-precision-left-right-alignment?noredirect=1&lq=1
--In LuaTeX, you can use the post_linebreak_filter to intercept the broken lines and
-- add some offsets. The sidebearings can be extracted from rawdata saved by luaotfload.
-- After adding the offsets, the hboxes have to be repacked to determine the new glue settings.
---updated for 1.09
--https://tex.stackexchange.com/questions/470276/perfect-alignment-luatex-and-sidebearings-part-ii
------------------------drop_sidebearing------------------------
local function drop_sidebearing(head, groupcode)
if tex.count['dropsidebearings'] == 0 then
return true
end
for n in node.traverse_id(node.id'hlist', head) do
local char = node.has_glyph(n.head)
if char then
local f = font.getfont(char.font)
if f.shared then
local kern = node.new(node.id'kern')
kern.kern = - f.shared.rawdata.descriptions[char.char].boundingbox[1]*f.size/1000
n.head = node.insert_before(n.head, char, kern)
end
end
for ch in node.traverse_id(node.id'glyph', n.head) do
char = ch
end
if char then
local f = font.getfont(char.font)
if f.shared then
local desc = f.shared.rawdata.descriptions[char.char]
local kern = node.new(node.id'kern')
kern.kern = - (desc.width-desc.boundingbox[3])*f.size/1000
node.insert_after(n.head, char, kern)
end
end
local new_list = node.hpack(n.head, n.width, 'exactly')
new_list.head = nil
n.glue_order = new_list.glue_order
n.glue_set = new_list.glue_set
n.glue_sign = new_list.glue_sign
node.free(new_list)
end
return true
end
luatexbase.add_to_callback('post_linebreak_filter', drop_sidebearing, 'Drop sidebearings after linebreaking')
\end{luacode*}
\setlength{\parindent}{0pt}
\renewcommand{\familydefault}{\sfdefault}
\begin{document}
\dropsidebearings=1
dropsidebearing =1 (no sideberarings)
\Huge F
\huge F
\LARGE F
\Large F
\large F
\dropsidebearings=0
dropsidebearing =0 (normal sideberarings)
\Huge F
\huge F
\LARGE F
\Large F
\large F
\end{document}
\hskip-0.5pt Factuur. – Marijn Mar 24 '21 at 14:59