With the current code the document gives the same reference twice.
\PassOptionsToPackage{square,numbers,comma,sort&compress,super}{natbib}
\documentclass[aps,prl, twocolumn, a4paper,superscriptaddress]{revtex4-2}
\usepackage{multibib}
\begin{document}
\bibliographystyle{plainnat}
\bibliography{mybib1}
\bibliographystylerec{plainnat}
\bibliography{mybib2}
\end{document}
multibib/natbibissues which there are a few of, butrevtexappears to be causing further issues. – Dai Bowen Apr 01 '23 at 15:00