You can specify the alignment via &.
Personally, I would not use any \quad but you may add them. In addition, I added commas. But these are just my recommendations. You might also want to have a look on https://ctan.org/pkg/lshort.
See also https://tex.stackexchange.com/a/31956/128553 for a different numbering scheme within the cases environment.
\documentclass{article}
\usepackage{amsmath}
\begin{document}
\begin{align}
\text{Minimize }
& \sum_{j=1}^{n} c_j x_j \
\text{s.t. }
& \sum_{j=1}^{n} f_{ij} x_j \geq 1, & i = 1, \ldots, m, \
& \sum_{j=1}^{n} g_{kj} x_j \leq h_k, & k = 1, \ldots, K, \
& x_j \in \left { 0, 1 \right }.
\end{align}
\begin{align}
\text{Minimize }
& \sum_{j=1}^{n} c_j x_j \
\text{s.t. }
& \begin{cases}
\displaystyle \sum_{j=1}^{n} f_{ij} x_j \geq 1, & i = 1, \ldots, m, \
\displaystyle \sum_{j=1}^{n} g_{kj} x_j \leq h_k, & k = 1, \ldots, K, \
\displaystyle x_j \in \left { 0, 1 \right }.
\end{cases}
\end{align}
\begin{align}
\text{Minimize }
& \sum_{j=1}^{n} c_j x_j \
\text{s.t. }
& \begin{cases}
\sum_{j=1}^{n} f_{ij} x_j \geq 1, & i &= 1, \ldots, m, \
\sum_{j=1}^{n} g_{kj} x_j \leq h_k, & k &= 1, \ldots, K, \
x_j \in \left { 0, 1 \right }.
\end{cases}
\end{align}
\end{document}

align, replace the\quqdby&&. You might benefit from reading about this in theamsmathusers guide. – barbara beeton Dec 12 '23 at 03:58