In case you want to suppress the numbering of sections (and subsections, etc) globally in the body of the document but still have them show up in the Table of Contents automatically, the easiest way to do so is to issue the command
\setcounter{secnumdepth}{0}
in the document's preamble. (The depth of a section-level command is "1", that of a subsection is "2", etc.) The following MWE illustrates how this would work; the two section-level and two subsection-level headers are unnumbered in the body of the text but show up automatically in the ToC:
\documentclass[a4paper]{article}
\setcounter{secnumdepth}{0}
\begin{document}
\tableofcontents
\section{Hello}
\subsection{Good morning}
\subsection{Good evening}
\section{Good-bye}
\end{document}
\section*{SN}\addcontentsline{toc}{section}{SN}– Gonzalo Medina Sep 06 '12 at 13:04