Please consider the following MWE. In addition to the xstick of the bottom x-axis (or primary x-axis) I would like to add a extra tick at the upper x-axis (or secondary x-axis).
\documentclass{article}
\usepackage{tikz}
\usepackage{pgfplots,pgfplotstable}
\usetikzlibrary{pgfplots,groupplots}
\begin{document}
\begin{tikzpicture}
\begin{groupplot}[
group style={
group size=2 by 2,
xlabels at=edge bottom,
ylabels at=edge left,
vertical sep= 1.5cm,
horizontal sep= 2cm,
every axis y label/.style={at={(ticklabel cs:0.5)},rotate=90,anchor=near ticklabel}
},
footnotesize,
xlabel=xlabel,
ylabel=very long label
,xtick={42,44,46,48}
,extra x ticks={41}
,extra x tick style={pos=right, grid=major,
tick label style={pos=left,font=\footnotesize,anchor=north}},
extra x tick labels={VLP},
]
\nextgroupplot[title=\#1]
\addplot[dashed] coordinates{(42, 255) (43, 1584) (44, 1296) (45, 432) (46, 972) (47, 540) (48, 1104) (49, 0)};
\addplot[blue] coordinates{(41, 608) (42, 608) (43, 1068) (44, 1068) (45, 870) (46, 654) (47,654) (48, 654) (49, 0)};
\nextgroupplot[title=\#2]
\addplot[dashed] coordinates{(42, 400) (43, 400) (44, 0) (45, 400) (46, 0) (47, 0) (48, 0) (49, 0)};
\addplot[blue] coordinates{(41, 267) (42, 267) (43, 267) (44, 200) (45, 200) (46, 0) (47, 0) (48, 0) (49, 0)};
\nextgroupplot[title=\#3]
\addplot[dashed] coordinates{(42, 1800) (43, 2100) (44, 1800) (45, 900) (46, 2100) (47, 2100) (48, 2100) (49, 0)};
\addplot[blue] coordinates{(41, 1613) (42, 1613) (43, 1613) (44, 1613) (45, 1613) (46, 1613) (47, 1613) (48,1613) (49, 0)};
\nextgroupplot[title=\#4]
\addplot[dashed] coordinates{(42, 6800) (43, 2800) (44, 2800) (45, 2800) (46, 2000) (47, 2800) (48, 0) (49, 0)};
\addplot[blue] coordinates{(41, 3600) (42, 3600) (43, 2799) (44, 2789) (45, 2708) (46, 2254) (47, 2254) (48, 0) (49, 0)};
\end{groupplot}
\end{tikzpicture}
\end{document}

\usetikzlibrary{pgfplots}in another MWE. Thx for the tip. – John Oct 19 '12 at 18:54