In theory, additive mixing Red color and Green color produces Yellow color.
In my mental model, additive mixing opaque Red and opaque Green will produce opaque Yellow.
But the following attempt, I got a result that is different from my mental model.
WHY?

Minimal Code (PSTricks)
\documentclass[dvipsnames,dvips,rgb]{minimal}
\usepackage{pstricks}
\begin{document}
\begin{pspicture}(3,3)
\psset{fillstyle=solid,opacity=0.5,linestyle=none}
\pscircle[fillcolor=red](1,1){1}
\pscircle[fillcolor=green](2,1){1}
\psframe[fillcolor=yellow](0,2)(3,3)
\end{pspicture}
\end{document}
Minimal Code (PGF/Tikz)
\documentclass[dvipsnames,dvips,rgb]{minimal}
\usepackage{tikz}
\begin{document}
\begin{tikzpicture}
\draw [fill=red,opacity=0.5](1,1) circle (1);
\draw [fill=green,opacity=0.5](2,1) circle (1);
\draw [fill=yellow,opacity=0.5] (0,2)--(0,3)--(3,3)--(3,2)--cycle;
\end{tikzpicture}
\end{document}
\fill [red] (0,0) circle (2cm) ; \fill [green] (0,1) circle (2cm) ;, which draws opaque circles, produces no yellowish region at all? – Antal Spector-Zabusky Jan 01 '11 at 22:58