I am not sure what the exact page width of the sig-alternate class is, but from your image this I appeared to be about 5.0in.
By using a p{} column type for the first column, eliminating the column soacing to the left of the first column and to the right of the last column, and reducing the inter column spacing with a @{\hspace{0.5em}} you can sqeeuze your table to make it fit:

Notes:
- The
showframe option of the geometry package was used to show the frame. And also adjust the page margins.
Code:
\documentclass{article}
\usepackage{ctable}
\usepackage[paperwidth=5.0in,showframe]{geometry}
\begin{document}
\begin{table}[h]
\centering
\begin{tabular}{@{}p{0.7in}r@{\hspace{0.5em}}r@{\hspace{0.5em}}r@{\hspace{0.5em}}r@{}}
\toprule
\multicolumn{1}{@{}c}{\small{QoS Attribute}} & \small{Sequential} & \small{Parallel} & \small{Loop} & \small{Conditional} \\
\midrule
\small{Response Time} & $\sum\limits_{i=1}^n q(s_i)$ & $\max\limits_{i=1}^n q(s_i)$ & k(q(s)) & $\max\limits_{i=1}^n q(s_i)$ \\
\midrule
\small{Availablity} & $\prod\limits_{i=1}^n q(s_i)$ & $\prod\limits_{i=1}^n q(s_i)$ & $q(s)^k$ & $\min\limits_{i=1}^n q(s_i)$ \
\midrule
\small{Throughput} & $\min\limits_{i=1}^n q(s_i)$ & $\min\limits_{i=1}^n q(s_i)$ & $q(s)$ & $\min\limits_{i=1}^n q(s_i)$ \
\bottomrule
\end{tabular}%
\caption{Add caption}
\label{tab:compositionalStructure}%
\end{table}
This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1 This is line 1
\end{document}
I downloaded the sig-alternate class (May 2012 version), and both the original and modified table seem to fit fine, so perhaps there are other settings you missed in your MWE:

Notes:
Code:
\documentclass{sig-alternate}
\usepackage{ctable}
\usepackage{showframe}
\begin{document}
\noindent
\begin{tabular}{rrrrr}
\toprule
\multicolumn{1}{c}{\small{QoS Attribute}} & \small{Sequential} & \small{Parallel} & \small{Loop} & \small{Conditional} \\
\midrule
\small{Response Time} & $\sum\limits_{i=1}^n q(s_i)$ & $\max\limits_{i=1}^n q(s_i)$ & k(q(s)) & $\max\limits_{i=1}^n q(s_i)$ \\
\midrule
\small{Availablity} & $\prod\limits_{i=1}^n q(s_i)$ & $\prod\limits_{i=1}^n q(s_i)$ & $q(s)^k$ & $\min\limits_{i=1}^n q(s_i)$ \\
\midrule
\small{Throughput} & $\min\limits_{i=1}^n q(s_i)$ & $\min\limits_{i=1}^n q(s_i)$ & $q(s)$ & $\min\limits_{i=1}^n q(s_i)$ \\
\bottomrule
\end{tabular}%
\bigskip
\noindent
\begin{tabular}{@{}p{0.7in}r@{\hspace{0.5em}}r@{\hspace{0.5em}}r@{\hspace{0.5em}}r}
\toprule
\multicolumn{1}{@{}c}{\small{QoS Attribute}} & \small{Sequential} & \small{Parallel} & \small{Loop} & \small{Conditional} \
\midrule
\small{Response Time} & $\sum\limits_{i=1}^n q(s_i)$ & $\max\limits_{i=1}^n q(s_i)$ & k(q(s)) & $\max\limits_{i=1}^n q(s_i)$ \
\midrule
\small{Availablity} & $\prod\limits_{i=1}^n q(s_i)$ & $\prod\limits_{i=1}^n q(s_i)$ & $q(s)^k$ & $\min\limits_{i=1}^n q(s_i)$ \
\midrule
\small{Throughput} & $\min\limits_{i=1}^n q(s_i)$ & $\min\limits_{i=1}^n q(s_i)$ & $q(s)$ & $\min\limits_{i=1}^n q(s_i)$ \
\bottomrule
\end{tabular}%
\end{document}
longtable,booktabs,ragged2eandarray. Makes great tables if you compensate fortabcolsep. – 1010011010 May 26 '14 at 00:19