\documentclass{article}
\usepackage{amsmath}
\begin{document}
\begin{alignat*}{3}
&\text{Case 1: } s^*\leq a&\quad &\hphantom{\leq} 2\beta \leq& 2a\alpha-4\lambda-\tau &\Rightarrow s^* = \frac{2\beta+4\lambda+\tau}{2\alpha}\\
&\text{Case 2: } a < s^* \leq b&\quad 2a\alpha-4\lambda+\tau &\leq 2\beta \leq& 2b\alpha-4\lambda+\tau &\Rightarrow s^*=\frac{2\beta+4\lambda-\tau}{2\alpha}\\
&\text{Case 3: } b < s^* \leq c&\quad 2b\alpha-2\lambda+\tau &\leq 2\beta \leq& 2c\alpha-2\lambda+\tau &\Rightarrow s^* = \frac{2\beta+2\lambda-\tau}{2\alpha}\\
&\text{Case 4: } c < s^* \leq d&\quad 2c\alpha+\tau &\leq 2\beta \leq& 2d\alpha+\tau &\Rightarrow s^* = \frac{2\beta-\tau}{2\alpha}\\
&\text{Case 5: } d < s^* \leq e&\quad 2d\alpha+2\lambda+\tau &\leq 2\beta \leq& 2e\alpha+2\lambda+\tau & \Rightarrow s^* = \frac{2\beta-2\lambda-\tau}{2\alpha}\\
&\text{Case 6: } e < s^*&\quad 2e\alpha+4\lambda+\tau &\leq 2\beta \hphantom{\leq}& &\Rightarrow s^* = \frac{2\beta-4\lambda-\tau}{2\alpha}
\end{alignat*}
\end{document}
The above code results in the PDF:

Everything is right except the 4th line. Why is the 2d\alpha+\tau aligning right? How can I get it to align immediately with \leq?


\documentclass{...}and ending with\end{document}. That may seem tedious to you, but think of the extra work it represents for TeX.SX users willing to help you. Help them help you: remove that one hurdle between you and a solution to your problem. – jub0bs Sep 30 '13 at 18:38