I would like to trace this figure, but I have difficulties in controlling the placement of arrows and numerical flows underneath the arrows.

The "sedimentary rock" node has to be split in two. Can you support some help. Thanks in advance.
\documentclass[tikz]{minimal}
\usepackage{tikz}
\usetikzlibrary{shapes}
\begin{document}
\begin{tikzpicture}
\node[rectangle,fill=red!70,text width=4cm,anchor=base] (atmosfera) at (5cm, 8cm) {Atmosphere\\ (carbon dioxide)};
\node[rectangle,fill=red!70,text width=4cm,anchor=base] (biosfera) at (0cm, 2.5cm) {Biosphere\\ (carbohydrates)};
\node[rectangle,fill=red!70,text width=4cm,anchor=base] (oceano) at (8cm, 0cm) {Ocean\\(bicarbonate ions)\\ $1.3\times10^{20}$};
\node[rectangle,fill=red!70,text width=4cm,anchor=base] (rochas) at (0cm, 0cm) {Sedimentary rocks};
\draw[->,out=-90,in=0,looseness=1, draw=blue] (atmosfera.south west) to node[midway, above, sloped] {Photosynthesis} (biosfera.east) ;
\draw[->,out=90,in=180,looseness=1, draw=blue] (biosfera.north) to node[midway, above, sloped] {Respiration and decay\\$10^{17}$} (atmosfera.west) ;
\draw[->,out=-90,in=90,looseness=1, draw=blue] (biosfera.west) to node[midway, above, sloped] {Burial\\ $3 \times 10^{14}$} (rochas.west) ;
\draw[->,out=90,in=-90,looseness=1, draw=blue] (rochas.north) to node[midway, above, sloped] {Vulcanism and weathering} (atmosfera.south) ;
\draw[->,out=90,in=120,looseness=1, draw=blue] (rochas.south east) to node[midway, above, sloped] {$10^{15}$} (oceano.north west) ;
\draw[->,out=.120,in=-60,looseness=1, draw=blue] (oceano.south) to node[midway, above, sloped] {Sedimentation} (rochas.west) ;
\draw[->,out=-90,in=90,looseness=1, draw=blue] (atmosfera.south) to node[midway, above, sloped] {Solution} (oceano.north) ;
\draw[->,out=90,in=0,looseness=1, draw=blue] (oceano.east) to node[midway, above, sloped] {Evaporation} (atmosfera.east) ;
\end{tikzpicture}
\end{document}


<pre>and</pre>tags, then it will be formatted as code rather than as plain text. – I Like to Code Jan 18 '14 at 18:00