Joseph Wright wrote a message to 10 package authors last weekend (and I am sure he does not mind quoting it here).
Hello all,
I've done a recent expl3 update in which I've remove functions
deprecated in 2013, following the pattern we've set up. A sweep of TeX
Live shows there are a few stray uses of \int_case:nnn, \tl_case:Nnn,
\str_case:nnn and \str_case_x:nnn, all of which should now end "F"
(e.g. \str_case:nnF). These are easy to miss (I've got one myself to
fix in siunitx), but updates of your code to match expl3 would be
welcome.
Where I can I've made pull requests on GitHub/BitBucket with fixes.
I've also asked that TL don't update the expl3 version until people
have a chance to address this.
Regards,
Joseph
So, MikTeX updated too quickly. Less than a week seems not enough for 10 package authors to update their packages.
Update: I updated mhchem. The upload to CTAN was made 2015-07-23. It will take a day to get approved, a day to distribute to the mirrors and a few extra days until you will eventually see it as a MiKTeX update.
This addendum might be useful for others, but is not related to the mhchem package: After correcting the signature (from :nnn to :nnF), the functions were renamed once again to correct the type of expansion they perform. \str_case_x:nn(TF) is now \str_case_e:nn(TF) (the x expansion is slightly different from the e expansion, and the latter is correct for these functions).
\documentclass{article}\usepackage{expl3}\ExplSyntaxOn\cs_generate_variant:Nn\str_case:nnn{Vnn}\begin{document}hi\end{document}? – Sean Allred Jul 23 '15 at 00:58kernel/command-not-defined;Control sequence \s undefined.andkernel/missing-colon;Function '\s' contains no ':'.. – Nessiesson Jul 23 '15 at 01:09\listfilesbefore\documentclassand post the output? – cfr Jul 23 '15 at 01:12566*versions from this week? TL is still giving me5630. Did they introduce a bug, do you think? – cfr Jul 23 '15 at 01:42graphics.cfgis the only thing which looks older than TL gives me. The rest is the same or newer, and I bet the newer is the problem here. – cfr Jul 23 '15 at 01:49fontspecandmhchemrely on a function which is considered deprecated and has now disappeared.... – cfr Jul 23 '15 at 02:01