The following code:
\begin{align*}
2(3-x) \leq 2 &\Leftrightarrow 6-2x &\leq 2 \\
& \Leftrightarrow -2x &\leq 2-6
\end{align*}
looks like this
does not align \leq, how one can align in this example the \leq signs? Thnak you!

&inaligntreat the intervening material in pairs, with each pair being handled as an independent equation, "centered" on the sign of relation. so to get the right-hand expressions to line up "to the left", insert two&before them. (i'll look for a duplicate; i know this has been answered before.) welcome to tex.sx. – barbara beeton Nov 03 '15 at 17:05