I have made a table in my document and the everything looks quite good to me. The issue is that when numbers with mixed signs appear in a column they are not aligned.
\documentclass{article}
\usepackage{caption}
\usepackage{subcaption}
\usepackage{booktabs}
\begin{document}
{\footnotesize
\begin{table}
\caption{ A table here for some values of energies ($cm^{-1}$)
\label{Energy_table} }
\begin{tabular}{p{0.25cm} p{1.60cm} p{1.0cm} p{1.0cm} p{1.0cm} p{0.001cm} p{1.60cm} p{1.1cm} p{1cm}p{1cm}}
\toprule
&\multicolumn{3}{c}{$A_{0}$} & & \multicolumn{3}{c}{$B_{1}$}\\ \cline{2-5} \cline{7-10}
$m$ & Theory & $\Delta^{a}$ & $\Delta^{b}$& $\Delta^{c}$ & & This work& $\Delta^{a}$ & $\Delta^{b}$& $\Delta^{c}$ \\ \cline{1-5} \cline{7-10}
1 & 297.4623 & -0.072 & -0.071 & -0.071 & & & 5.667 & 2.625 & \\
2 & 984.5495 & -0.092 & -0.059 & -0.099 & & 2814.507 & -0.032 & -0.043 & -0.039 \\
\multicolumn{8}{c}{} \\
&\multicolumn{3}{c}{$C_{0}$} & & \multicolumn{3}{c}{$D_{1}$}\\ \cline{2-5} \cline{7-10}
$n$ & This work & $\Delta^{a}$ & $\Delta^{b}$& $\Delta^{c}$ & & This work& $\Delta^{a}$ & $\Delta^{b}$& $\Delta^{c}$ \\ \cline{1-5} \cline{7-10}
0 & 46.5495 & -0.099 & -0.099 & -0.099 & & 2814.507 & -0.032 & -0.043 & -0.039 \\
& & & & & & & & &\\
& & & & & & & & &\\
& & & & & & & & & \\
\bottomrule
\end{tabular}
\end{table}}
\end{document}
In the image this is visible in the B1 sub-table (right top).
How to properly align based on the decimal.
(I tried to follow this answer but I could not compile. I do not understand the commands in this answer about how to set the number of columns ! Aligning numeric values in table)

cline. – Thomas Jun 08 '16 at 11:46