Sorting options are described in section 3.5 of the biblatex manual, with appropriate cross-referencing to the entry fields described in section 2.2 that are used to create entries in the bib resource file.
From the manual it can quickly be discovered that there are at least two ways to give you what you want.
The first, and the most obvious, option is to use a presort field (p27). Using presort permits intimate ordering of the bibliography by listing the items in the order you want them to appear. The second option is to use the sortname field. It overrides the default use of the author or editor (p27), which here, is the list of the names of two authors, not just the first name.
Both solutions are provided in this MWE.
\documentclass[a4paper,10pt]{article}
\usepackage{filecontents}
\usepackage[style=numeric,
backend=biber,
]{biblatex}
\addbibresource{refs.bib}
\DeclareNameAlias{default}{last-first}
% Option 1 using sortname which overrides author as the primary sort field
%\begin{filecontents*}{refs.bib}
% @article{Doe10a,
% author={Jane Doe and Steve Aart},
% sortname={Jane Doe},
% year={2010}
% }
% @article{Doe04,
% author={Jane Doe and Mark Bart},
% sortname={Jane Doe},
% year={2004},
% }
% @article{Doe10b,
% author={Jane Doe and Mike Smith},
% sortname={Jane Doe},
% year={2010}
%}
%\end{filecontents*}
% Option 2: Uses presort so the bibliography is printed in a given order, here: A, B, C
\begin{filecontents*}{refs.bib}
@article{Doe10a,
author={Jane Doe and Steve Aart},
presort={B},
year={2010}
}
@article{Doe04,
author={Jane Doe and Mark Bart},
presort={A},
year={2004},
}
@article{Doe10b,
author={Jane Doe and Mike Smith},
presort={C},
year={2010}
}
\end{filecontents*}
\begin{document}
\nocite{*}
\printbibliography
\end{document}

In future questions, please post a MWE showing what you have attempted. It makes it much easier for people to help you.
\DeclareSourcemapto automatically populate the sortname field with the first name. – PLK Oct 18 '16 at 10:57