You can use pst-node and a latex -> dvips -> ps2pdf (or xelatex) compile sequence to produce the following:

\documentclass{article}
\usepackage{pst-node}% http://ctan.org/pkg/pst-node
\begin{document}
\[
\begin{array}{*{9}{c}}
e_{1} & = & 0 & . & \rnode{A}{d_{1}^{1}} & d_{1}^{2} & d_{1}^{3} & d_{1}^{4} & ... \\
\\
e_{2} & = & 0 & . & d_{2}^{1} & d_{2}^{2} & d_{2}^{3} & d_{2}^{4} & ... \\
\\
e_{3} & = & 0 & . & d_{3}^{1} & d_{3}^{2} & d_{3}^{3} & d_{3}^{4} & ... \\
\\
e_{4} & = & 0 & . & d_{4}^{1} & d_{4}^{2} & d_{4}^{3} & \rnode{B}{d_{4}^{4}} & ... \\
... \\
\end{array}
\]
\ncline[nodesep=-1.2\baselineskip,linewidth=.4pt]{->}{A}{B}% Draw line
\end{document}
\rnode{<node>}{<stuff>} makes one able to reference <stuff> via <node>. \ncline is used to draw the node connection lines between the specified nodes. Since this draws on the rich pstricks library, you can modify the colour, width, presentation and style of the line as needed.
Note that I've changed your "entirely mathematical tabular" to an array environment, which is its intended use. Additionally, instead of centering it (via the center environment), I've place the entire array in a display math environment (using \[ and \]).
More pronounced arrow definitions is possible via some of the basic pstricks arrow head modifications. One could use the options (key-value) arrowsize=<dim> <num>, arrowlength=<dim>, arrowinset=<num> or arrowscale=<factor>. Here is some detail from the pstricks documentation (p 28, section 15 Arrowheads and such):

For example, try
\ncline[nodesep=-1.2\baselineskip,linewidth=.4pt,arrowsize=3pt 2]{->}{A}{B}% Draw line
{}button above the text field), the code will be marked as such. This also works for inline code. – Torbjørn T. Dec 09 '11 at 18:07