This answer may be more generic than specifically relating to TikZ/PGF.
(La)TeX is a macro-based language, so it does not work as expected compared to other languages when dealing with "arrays". For example, while \names[2] should yield Laura where
\def\names{Katie, Frank, Laura, Joe}
(indexing from 0), (La)TeX considers [2] to have no connection to \names. As such, you're more likely to obtain the output Katie, Frank, Laura, Joe[2] - a concatenation of \names (as it is defined) and [2].
In order to allow for indexing like one typically would using arrays, you would need some other functionality. Here's an example of a list parser that works like you would expect arrays do:

\documentclass{article}
\usepackage{xparse}% http://ctan.org/pkg/xparse
\usepackage{etoolbox}% http://ctan.org/pkg/etoolbox
\newcounter{listtotal}\newcounter{listcntr}%
\NewDocumentCommand{\names}{o}{%
\setcounter{listtotal}{0}\setcounter{listcntr}{-1}%
\renewcommand*{\do}[1]{\stepcounter{listtotal}}%
\expandafter\docsvlist\expandafter{\namesarray}%
\IfNoValueTF{#1}
{\namesarray}% \names
{% \names[<index>]
\renewcommand*{\do}[1]{\stepcounter{listcntr}\ifnum\value{listcntr}=#1\relax##1\fi}%
\expandafter\docsvlist\expandafter{\namesarray}}%
}
\begin{document}
\newcommand{\namesarray}{Katie, Frank, Laura, Joe}%
\verb|\names:|\ \names \par
\verb|\names[2]:|\ \names[2] \par
\verb|\names[0]:|\ \names[0] \par
\verb|\names[5]:|\ \names[5]
\end{document}
The idea here is to store the names in an array \namesarray and then define a macro (or "function") that takes an optional argument. If no argument is supplied (i.e., you just use \names), then you print the entire \namesarray. If an argument is supplied (of the form \names[<index>]), parse the list sequentially to find that item that matches <index> and print it.
The list parser relies on etoolbox's \docsvlist and enumerator \do.
foreachloop? – percusse Feb 19 '12 at 17:11\begin{tikzpicture} \def\mylist{Laura,Katie,Frank,Joe} \foreach[count=\xi] \x in \mylist \node[minimum width=1cm] (n\xi) at (\xi,\xi) {\x}; \end{tikzpicture}. The quotes are needed when you plugin your list into a macro and to protect the text from a math parser! – percusse Feb 19 '12 at 17:19