If you do not evaluate \j to an integer, you get numbers like 1.0, in which .0 is interpreted as the east anchor. So all I did was to replace [evaluate=\i as \j using \i - 1] by [evaluate=\i as \j using {int(\i - 1)}] to get
\documentclass[margin=2pt]{standalone}
\usepackage{tikz}
\usetikzlibrary{positioning,fit}
\newcommand{\PL}[3][]{
\node[thick,circle,draw,minimum size=0.5cm,inner sep=0,outer sep=0,label=left:#3,#1](#2){};
\draw[thick,#1] (#2.south west) -- (#2.north east);
}
\begin{document}
\begin{tikzpicture}
\PL{L1}{1}
\PL[below=0.1 of L1]{L2}{2}
\PL[below=0.1 of L2]{L3}{3}
\PL[below=0.1 of L3]{L4}{C}
\PL[below=0.1 of L4]{L5}{R}
\PL[below=0.1 of L5]{L6}{RC}
\PL[below=0.1 of L6]{L7}{RH}
\node[fit=(L1)(L7), draw] {};
\end{tikzpicture}
\begin{tikzpicture}
\PL{L1}{1}
\foreach \i [evaluate=\i as \j using {int(\i - 1)}] in {2,...,7} {
\PL[below=0.1cm of L\j]{L\i}{\i}
}
\node[fit=(L1)(L7), draw] {};
\end{tikzpicture}
\end{document}

ADDENDUM: Since @AndréC added an answer which is IMHO not really to the point of the original question, I add something that is to the point of the original question as well as some sort of a response to AndréC.
- You can avoid all this by using
remember.... And you can, of course, attach the labels of your left diagram, just declare \i to be the count.
- Using a path picture to strike out a node is one way, what you are doing is IMHO at least equally good, and one can also use
strike out that comes with shapes.misc. None of this, however, is IMHO at the heart of the question.
So here is an example (but if I was you I would keep your way of striking the node out, probably using a path picture is more elegant than strike through, though).
\documentclass[tikz,border=3.14mm]{standalone}
\usetikzlibrary{positioning,fit,shapes.misc}
\newcommand{\PL}[3][]{
\node[thick,strike out,
draw,minimum size=0.35cm,inner sep=0,outer sep=0,#1](#2-inner){};
\node[draw,circle,inner sep=0,fit=(#2-inner),outer sep=1pt,label=left:#3](#2){};
}
\begin{document}
\begin{tikzpicture}
\PL{L1}{1}
\foreach \X [count=\i starting from 2,remember=\i as \j (initially 1)]
in {2,3,C,R,RC,RH} {
\PL[below=0.1cm of L\j]{L\i}{\X}
}
\node[fit=(L1)(L7), draw] {};
\end{tikzpicture}
\end{document}

\typeouts to your code, so if you add\typeout{\j}to your code you will see1.0,2.0and so on, which may help to get on track.) – Nov 24 '18 at 20:261.0. Congratulations! – AndréC Nov 24 '18 at 21:31