Roughly speaking, XeTeX (and LuaTeX) extends number of math fonts from 16 to 256, but currently (texlive 2019) latex2e only allow math alphabets in full range 0-255, and restrict symbol fonts 0-15 (changed in this commit, in 2015).
As a XeTeX user, how can I use the full 0-255 symbol fonts?
Related info:
An extension to more than 16 symbol fonts needs more extensive changes replacing all uses of
\mathchardef\mathaccent\radicaletc by\U...versions.David Carlisle Mar 12 '15, from this comment
Maybe I should learn the usage of \U... primitives, documented in texdoc xetex, sec. 2.3.
