Suppose we have the following:
\documentclass{standalone}
\usepackage{tikz}
\usepackage{pgfplots}
\usepackage{pgfplotstable}
\pgfplotsset{compat=1.16}
\usepgfplotslibrary{external}
\tikzexternalize
\begin{document}
\begin{tikzpicture}
\begin{axis}[%legend cell align={&+},?
legend entries={a+b, aaaa+bbb},]
\addplot {x};
\addplot {x^2};
\end{axis}
\end{tikzpicture}
\end{document}
Is it possible to align text in a legend with respect to a certain character? e.g. like we might do in an align environment
\begin{align}
a &+ b\\
aaaa &+ bbb
\end{align}
I know we can do legend cell align=left etc. but this will only work for the above case when the legend entries themselves meet a certain criteria.
As an aside, where do I find a comprehensive documentation page for pgfplots? I have been referring to this although it is not all inclusive.

pgfplotson CTAN, on this page. – Vincent Jan 23 '20 at 03:24