My working example is:
\documentclass[a4paper, 12pt]{scrreprt}
\usepackage{amsmath}
\usepackage{braket}
\usepackage{mleftright}
\begin{document}
\begin{subequations}
\label{ComputationInnProd}
\begin{align}
\label{ComputationInnProdDiscr}
\langle \underbrace{ \mleft( \sum_{\alpha'} \psi_{\alpha'}^* \bra{\alpha'} \mright) }_{\bra{\psi}} \vert \underbrace{ \mleft( \sum_{\alpha''} \varphi_{\alpha''} \ket{\alpha''} \mright) }_{ \ket{\phi} } \rangle = \sum_{\alpha', \alpha''} \psi_{\alpha'}^* \varphi_{\alpha''} \braket{\alpha' \vert \alpha''} = \\
\sum_{\alpha',\alpha''} \psi_{\alpha'}^* \varphi_{\alpha''} \delta_{\alpha' \alpha''} = \sum_{\alpha'} \psi_{\alpha'}^* \varphi_{\alpha'}, \\
\label{ComputationInnProdCont}
\langle \underbrace{ \mleft( \int {d\alpha'} \psi^* \mleft( \alpha' \mright) \bra{\alpha'} \mright) }_{\bra{\psi}} \vert \underbrace{ \mleft( \int {d\alpha''} \varphi \mleft( \alpha'' \mright) \ket{\alpha''} \mright) }_{ \ket{\phi} } \rangle = \int {d\alpha'} \int {d\alpha''} \psi^* \mleft( \alpha' \mright) \varphi \mleft( \alpha'' \mright) \braket{\alpha' \vert \alpha''} = \\
\int {d\alpha'} \int {d\alpha''} \psi^* \mleft( \alpha' \mright) \varphi \mleft( \alpha'' \mright) \delta \mleft( \alpha' - \alpha'' \mright) = \int {d\alpha'} \psi^* \mleft( \alpha' \mright) \varphi \mleft( \alpha' \mright),
\end{align}
\end{subequations}
\end{document}
I want the first two equations to belong to subequation 0.1a and have the ComputationInnProdDiscr label and the latter two to be grouped as subequation 0.1b and have the label ComputationInnProdCont for future reference.
This code produces the following output:

I've marked each of the equality signs that I want to be aligned with each other in red and green, respectively. I'm also open to suggestions for what would make this more readable because it does not look particularly pretty.



\begin{split}\end{split}. See here https://tex.stackexchange.com/questions/17528/show-equation-number-only-once-in-align-environment – Elad Den May 20 '20 at 09:57