So, essentially I want to do exactly what is shown here. This has worked beautifully for me using miktex under Windows, but now I'm working under Ubuntu and have just installed the 2020 version of TeX Live. Here, I get the error message Package pgf Error: No shape named 'arccenter' is known .... So I would interpret this in a way that some of the internal workings of chemfig have changed so that the center of the ring is no longer called 'arccenter'? Is there a new name for that node that I could specify?
MWE:
\documentclass[a4paper,10pt]{article}
\usepackage[utf8]{inputenc}
\usepackage{chemfig}
\begin{document}
\chemfig[atom sep=.9cm]{**[,,,late options={name=arccenter,label=center:+}]5(-----)}
\end{document}
(I would have preferred to just add a comment to the existing question, however, I don't have enough reputation...

