The simplest way to manually insert a line break in a field content in the bibliography is to write \\ into the .bib entry. Of course this is not a very sustainable solution, since .bib files are supposed to be re-usable and this is a very situation-dependent fix. In general I would advise against putting those kind of ad hoc fixes into the .bib file because they could come back and bite you in different situations.
Even though I wouldn't recommend it, the following certainly works
\documentclass[oneside,11pt,draft]{book}
\usepackage[semibold,tt=false]{libertine}
\usepackage{libertinust1math}
\usepackage[
expansion=false,
tracking=smallcaps,
letterspace= 40,
final
]{microtype}
\usepackage[style=chem-acs,
maxbibnames=99, maxcitenames=99,
articletitle=true, chaptertitle=true,
doi=true,
defernumbers=true,
refsection=chapter,
]{biblatex}
\begin{filecontents}{\jobname.bib}
@ARTICLE{Trulsson2010,
author = {Trulsson, Martin and Algotsson, Jenny
and Forsman, Jan and Woodward, Clifford E.},
title = {Differential\Capacitance of Room Temperature
Ionic Liquids: The Role of Dispersion Forces},
journal = {J. Phys. Chem. Lett.},
year = {2010},
volume = {1},
pages = {1191--1195}
}
\end{filecontents}
\addbibresource{\jobname.bib}
% to fake the labelnumber
\DeclareFieldFormat{labelnumberwidth}{\mkbibparens{196}}
\begin{document}
\cite{Trulsson2010}
\printbibliography
\end{document}

Instead I would try to get rid of the overful box by using one of the methods discussed in How to adjust the breaking in the bibliography?.
In this example a bit of \emergencystretch helps (.1em is enough here).
\documentclass[oneside,11pt,draft]{book}
\usepackage[semibold,tt=false]{libertine}
\usepackage{libertinust1math}
\usepackage[
expansion=false,
tracking=smallcaps,
letterspace= 40,
final
]{microtype}
\usepackage[style=chem-acs,
maxbibnames=99, maxcitenames=99,
articletitle=true, chaptertitle=true,
doi=true,
defernumbers=true,
refsection=chapter,
]{biblatex}
\appto\bibfont{\setlength{\emergencystretch}{.1em}}
\begin{filecontents}{\jobname.bib}
@ARTICLE{Trulsson2010,
author = {Trulsson, Martin and Algotsson, Jenny
and Forsman, Jan and Woodward, Clifford E.},
title = {Differential Capacitance of Room Temperature
Ionic Liquids: The Role of Dispersion Forces},
journal = {J. Phys. Chem. Lett.},
year = {2010},
volume = {1},
pages = {1191--1195}
}
\end{filecontents}
\addbibresource{\jobname.bib}
% to fake the labelnumber
\DeclareFieldFormat{labelnumberwidth}{\mkbibparens{196}}
\begin{document}
\cite{Trulsson2010}
\printbibliography
\end{document}

But if you have many tricky references, setting the bibliography ragged right might be a better option.