I tried to use the code provided in this thread to use the Computer Modern italics' ampersand in a document typesetted in Libertine. However this only works in the "body" of the text but not in section titles.
\documentclass[a4paper]{article}
\usepackage{libertine}
\makeatletter
\DeclareRobustCommand*{&}{%
\nfss@text{%
\fontfamily{cmr}%
\selectfont
\itshape
\symbol{ `&}%
}%
}
\begin{document}
\section{Image & Direct Image}
Image & Direct Image
\end{document}
Any help appreciated.

