Here an idea similar to Οὖτις's answer but trying to improve spacing. The trouble is that simply scaling \Cup does not work well, because the glyph sticks outside of its bounding box if compared to \bigcup:
\fboxrule.1pt \fboxsep-\fboxrule
\fbox{$\Cup$} \fbox{$\displaystyle\bigcup$}

For the scaling to work properly (and to obtain decently placed limits) we must first add some vertical padding.
\documentclass{article}
\usepackage{graphicx}
\usepackage{amsmath}
\usepackage{amssymb}
\makeatletter
\newcommand*{\bigCup}{\mathop{\mathpalette\big@Cup\relax}\slimits@}
\newcommand*{\big@Cup}[2]{%
\setbox\z@=\hbox{\m@th$#1\Cup$}%
\setbox\z@=\vtop{\vbox{\kern.2\ht\z@\copy\z@}\kern.1\ht\z@}%
\setbox\tw@=\hbox{\m@th$#1\bigcup$}%
\vcenter{\hbox{\resizebox{!}{1.4\ht\tw@}{\box\z@}}}%
}
\makeatother
\begin{document}
D: $\displaystyle\bigcup_a^b c \qquad \displaystyle\bigCup_a^b c$\par\medskip
T: $\bigcup_a^b c \qquad \bigCup_a^b c$\par\medskip
S: $\scriptstyle\bigcup_a^b c \qquad \bigCup_a^b c$\par\medskip
SS: $\scriptscriptstyle\bigcup_a^b c \qquad \bigCup_a^b c$
\end{document}

Short comments:
- One could try making the new symbol thinner but that starts deforming lines a wee bit too much for my taste.
- The
\slimits@ comes from amsmath and is used by all sum-like big operators. It will obey the sumlimits/nosumlimits package options.
\big upand a\cup, although the fact that this symbol does not otherwise exist would give me pause. – Don Hosek Jul 19 '21 at 05:20\ccupcode. – M. Logic Jul 19 '21 at 07:49\Cupfrom theamssymb-package what you are looking for, at least for the "small" symbol? I used http://detexify.kirelabs.org/classify.html to search for such a symbol. – Οὖτις Jul 19 '21 at 08:08amssymb! However, there doesn't seem to be a "big" version. – Castor Jul 19 '21 at 23:23