I tried relative coordinates, but couldn't put a coordinate in to make angles. Is this possible?
\documentclass{standalone}
\usepackage{tikz}
\usetikzlibrary{calc}
\usetikzlibrary{quotes,angles,calc,plotmarks,decorations.text}
\begin{document}
\begin{tikzpicture}
\draw[red,fill=red] (3:0) circle (.5ex);
%\draw[help lines] (-1,0) grid (5,5);
%\draw (0,0) --++(2,0) --++(72:2)--++(144:1.75)--++(210:1.75) --cycle ;
\draw (0,0) --(2,0) -- (2.5,2) -- (1,3) --(-0.5,2) --cycle ;
\coordinate (a) at (0,0);
\coordinate (b) at (2,0);
\coordinate (c) at (2.5,2);
\coordinate (d) at (1,3);
\coordinate (e) at (-0.5,2);
\node[align=center, below ] at (a) {1};
\node[align=center, below ] at (b) {2};
\node[align=center,right ] at (c) {3};
\node[align=center,above ] at (d) {4};
\node[align=center,left ] at (e) {5};
%\pic [draw, -, "$\alpha_0$", angle eccentricity=1.5] {angle = c--b--a};
\pic [draw, -, "$\alpha_1$", angle eccentricity=1.5] {angle = a--e--d};
\pic [draw, -, "$\alpha_2$", angle eccentricity=1.5] {angle = e--d--c};
\pic [draw, -, "$\alpha_3$", angle eccentricity=1.5] {angle = d--c--b};
\pic [draw, -, "$\alpha_3$", angle eccentricity=1.5] {angle = b--a--e};
\draw pic[draw,fill=green!30,angle radius=0.4cm,"$ $" shift={(0mm,-5mm)}] {angle= c--b--a};
\end{tikzpicture}
\end{document}

\draw[blue] (0,0) --++(2,0) --++(72:2)--++(144:2)--++(216:2) --cycle;The interior angles are 180 - 72 = 108 degrees. – John Kormylo Jul 28 '23 at 21:21