The problem I am facing is that I am typesetting with MinionPro-Regular.otf as the main font and MinionPro-Cn.otf for the captions. However I have to declare only one math font for the whole document, thus math symbols and little siunitx things are not condensed.
Unfortunately \setmathsfont from mathspec does work only once in the preamble. Is there a way to change math font as you change the text font with fontspec? I don't need to typeset big formulas in captions only some numbers which are typeset using siunitx.
MWE:
\documentclass[10pt,a4paper]{memoir}
\usepackage[english]{babel}
z\usepackage[detect-all]{siunitx}
\usepackage[MnSymbol]{mathspec}
\setmathfont[range=\mathup/{num,latin,Latin,greek,Greek}]{MinionPro-Regular.otf}
\setmathfont[range=\mathbfup/{num,latin,Latin,greek,Greek}]{MinionPro-Bold.otf}
\setmathfont[range=\mathit/{num,latin,Latin,greek,Greek}]{MinionPro-It.otf}
\setmathfont[range=\mathbfit/{num,latin,Latin,greek,Greek}]{MinionPro-BoldIt.otf}
\defaultfontfeatures{Ligatures={TeX,NoCommon},Scale=MatchLowercase}
\setmainfont[BoldFont=MinionPro-Bold.otf,
ItalicFont=MinionPro-It.otf,
BoldItalicFont=MinionPro-BoldIt.otf,
Color=black]{MinionPro-Regular.otf}
\newfontfamily\captionfont[ItalicFont=MinionPro-MediumCnIt.otf]{%
MinionPro-Regular.otf}
\newcommand*{\mathtext}{\SI{2.3}{\micro\metre} %
2.3,μm $x=2.3,\mu m$}
\begin{document}\noindent
{\normalfont\itshape\mathtext} \
{\captionfont\itshape\mathtext}\
\end{document}
Output:

If you look carefully the \mu symbol in siunitx in the second line is chosen from \normalfont not \captionfont. Also although I am using Mnsymbol the symbols are still from Computer Modern.
\usepackage{MnSymbol}? – egreg Nov 23 '12 at 21:15