For Blender 2.8+ the paper model addon is available at GitHub
Quoting the manual at http://addam.github.io/Export-Paper-Model-from-Blender/
Install
The script is included in Blender 2.80. Just enable Import-Export:
Export Paper Model in Blender Preferences → Addons.
If you need something special and know what you’re doing, you may
download and install a recent version. There is also another version
for Blender 2.79.
How to Use
An optional step before start is to mark edges where the model will be
cut. From the Properties editor, call the Unfold operator on the
selected model. The edges will get marked as Edit mode Seams, you can
edit them in any way you like. The script will use the seams you mark
and mark some more as necessary.
All the show happens when you choose File → Export → Paper Model. A
File Browser appears, which also allows you to change the export
settings in its bottom-left corner.
Then (if everything goes well), the script saves the file without
talking. In the settings, if you switch No Texture to something else,
Cycles' Bake functionality will be exploited to render the images.
That may take some time.
The file format is PDF and should be ready to print. If you want to
edit the net by hand, you may prefer exporting to SVG and using a
vector editor such as Inkscape.
Advanced Usage
A humble panel is in the Properties panel in Object Data section.
Currently it gives you an overview of how the net will be split into
parts (aka. islands). It can show one of them directly in the 3D view,
highlighted in orange. You can edit the name of each island and give
it a three-letter abbreviation that will be used on the sticking tabs.