
In other words you want to find the triangle type that has the biggest ratio between area and perimeter squared.
First, let us show that it has to be isosceles triangle. Suppose the opposite, that the triangle $ABC$ is optimal. Draw line through point $C$ parallel with $AB$ and find the mirror point $A'$ of $A$ with respect to that line. Line $BA'$ meets the parallel line at point $C_1$.
Obviously, triangles $ABC$ and $ABC_1$ have the same area but triangle $AMC_1$ has smaller perimeter because:
$$AC_1+BC_1=A'C_1+C_1B<BC+CA'=BC+AC$$
So triangle $ABC$ is not optimal and we should consider only triangles that are isosceles.
Supose that the perimeter $P=2s$ is fixed, base of the thriangle is equal to $a$ and leg to $b$. Let us maximize the area.
$$b=s-\frac a2$$
$$h=\sqrt{b^2-\frac{a^2}{4}}$$
$$h=\sqrt{(s-\frac a2)^2-\frac{a^2}{4}}$$
$$h=\sqrt{s^2-as}$$
$$A=\frac{ah}2=\frac12\sqrt{a^2s^2-a^3s}$$
So the area is maximized when the function
$$f(a)=a^2s^2-a^3s$$
...has maximm value. By solving equation:
$$f'(a)=0$$
...we get:
$$2as^2-3a^2s=0\implies a=\frac{2s}{3} \implies a=b=\frac P3$$
So the most "circular" triangle is actually an equilateral triangle.