I just came across this ! (backslash exclamation mark) in the code for a table in somebody else's tex and I was wondering what it does.
\begin{table}[hbt]
\centering
\resizebox{\columnwidth}{!}{%
\setlength\extrarowheight{1pt}
\begin{tabular}{l | c c c | c r}
\toprule
\textbf{Thing} & $a$ & $b$ & $c$ & $d$ & $e$\\
\midrule
Stuff & \!\!100\!\! & \!\!$10^{6}$\!\! & \!\!$\pi_0$\!\! & $\sigma$ & $2^{30}$\\
\bottomrule
\end{tabular}%
}
\end{table}
My tex editor says unrecognized command but it compiles just fine. I've tried on overleaf and it seems to tighten the table somehow. Does anybody know more?

\!is a negative space, see https://tex.stackexchange.com/questions/9091/what-is-the-right-way-to-use-the-spacing-command for more information. – BambOo Oct 16 '18 at 09:13[I have seen this in actual documents. Disclaimer: don't do this. Seriously.]
– CompuChip Oct 16 '18 at 20:44