Another solution:
\documentclass{article}
\usepackage{geometry}
\usepackage{mathtools}
\DeclarePairedDelimiter{\abs}{\lvert}{\rvert}
\begin{document}
\begin{equation*}
V_{i,j} =
\begin{Bmatrix}
\displaystyle (Q_{1}D_{i}^{d} + Q_{2}D_{i}^{o})W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu}; D_{i}^{d} + D_{i}^{o} \leq W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu}\\[3ex]
\displaystyle Q_{1}D_{i}^{d}W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu}; D_{i}^{d} \leq W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu} < D_{i}^{d} + D_{i}^{o}\\[3ex]
\displaystyle 0; W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu} < D_{i}^{d}
\end{Bmatrix}
\end{equation*}
\end{document}

P.S. I've added geometry to avoid the equation going into the margin.
Update
If you want all the math in the document to be written in display style, you can declare \everymath{\displaystyle};
\documentclass{article}
\usepackage{geometry}
\usepackage{mathtools}
\DeclarePairedDelimiter{\abs}{\lvert}{\rvert}
\everymath{\displaystyle}
\begin{document}
\begin{equation*}
V_{i,j} =
\begin{Bmatrix}
(Q_{1}D_{i}^{d} + Q_{2}D_{i}^{o})W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu}; D_{i}^{d} + D_{i}^{o} \leq W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu}\\[3ex]
Q_{1}D_{i}^{d}W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu}; D_{i}^{d} \leq W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu} < D_{i}^{d} + D_{i}^{o}\\[3ex]
0; W_{j}\ln{\mkern -7mu}\left(1 + \frac{G_{i,j}\abs{h_{i,j}}^{2}P_{i,j}}{\sigma_{i,j}^{2}}\right){\mkern -5mu} < D_{i}^{d}
\end{Bmatrix}
\end{equation*}
\end{document}
V_{i,j}is equal to the material to the left of the semicolon if the statement on the right is true? If that's the case (pun intended), have you tried using thecasesenvironment provided by theamsmathpackage? – Mico Mar 25 '14 at 20:06