We can write the distribution $f(k)$ as $f(k)=g(k)+e^{-1}$, where $g(k)$ is the $L^1$ function given by
$$g(k)=e^{-1}\left(e^{a^2/(a^2+k^2)}-1\right)$$
The Fourier transform of $g$ is given by
$$\begin{align}
\mathscr{F}\{g\}(x)&=e^{-1}\int_{-\infty}^\infty \left(e^{a^2/(a^2+k^2)}-1\right)e^{ikx}\,dk\\\\
&=|a|e^{-1}\int_{-\infty}^\infty \left(e^{1/(1+k^2)}-1\right)e^{ik(x|a|)}\,dk
\end{align}$$
According to WolframAlpha, there is no result found in terms of standard functions. You could try writing $e^{1/(1+k^2)}-1=\sum_{n=1}^\infty \frac{1}{n!(1+k^2)^n}$ and seeing if that leads to anything useful.
In this section, we find a recursive equation for the function $f_n(t)$ where
$$f_n(t)=\int_{-\infty}^\infty \frac{e^{ikt}}{(1+k^2)^n}\,dk\tag1$$
For $n=1$, it is easy to show that $f_1(t)=\pi e^{-|t|}$. Now, for $n>2$ we differentiate $(1)$ twice to find that
$$f_n''(t)-f_n(t)=-f_{n-1}(t)\tag 2$$
with $f_n'(0)=0$ and $f_n(0)=\int_{-\infty}^\infty \frac1{(1+k^2)^n}\,dk=\pi\frac{(2n-3)!!}{(2n-2)!!} $ (See THIS ANSWER).
The general solution to $(2)$ can be written in terms of the Green function (or Green's function) for the ODE $y''(x)-y(x)=\delta(x)$, along with the prescribed initial conditions. We are now equipped with a recursive algorithm to calculate $f_n(t)$ for any $n$.
EDIT:
As @Metamorphy pointed out, we can express the integral $\int_{-\infty}^\infty \frac{e^{ikx|a|}}{(1+k^2)^n}\,dk$ in terms of the second kind modified Bessel function. Specifically, we have
$$\begin{align}\int_{-\infty}^\infty \frac{e^{ikx|a|}}{(1+k^2)^n}\,dk&=2\int_0^\infty \frac{\cos(k|xa|)}{(1+k^2)^n}\,dk\\\\
&=\frac{\sqrt{\pi}\,|xa|^{n-1/2}}{2^{n-3/2}(n-1)!}K_{n-1/2}(|xa|)\tag3
\end{align}$$
Using $(3)$ we can write
$$\mathscr{F}\{f\}(x)=2\pi e^{-1}\delta(x)+|a|e^{-1}\sqrt{\pi}\sum_{n=1}^\infty \frac{K_{n-1/2}(|xa|)|xa|^{n-1/2}}{2^{n-5/2}n!(n-1)!} $$
Mark: This looks like a complete answer, I just have one question, can you comment on what happens in the case of $a >> k$? I am inclined to believe that $f(k)$ can be approximated to Gaussian in that case, am I right? – user35952 Nov 23 '22 at 03:02