If you restrict the domain where to look for roots, Reduce can often find them and will return Root objects which can be used in exact symbolic calculations. Even better, it guarantees to give you all roots in that domain.
Reduce[1 + 1/2^x + 1/3^x == 0 && Abs[x] < 5, x]
(* x == Root[{1 + 3^#1 + E^(-(Log[2] - Log[3]) #1) &, 0.4543970081950240272783427420109442288880772534469111379406 - 3.5981714939947587422049363529208471165604257466288393398421 I}] ||
x == Root[{1 + 3^#1 + E^(-(Log[2] - Log[3]) #1) &, 0.4543970081950240272783427420110 + 3.5981714939947587422049363529208 I}] *)
When looking for real roots, the typical way to restrict the domain is something similar to 0 < x < 1. We're looking for complex roots her so I used Abs[x] < 5.
Related:
To use the FindRoots2D function from the linked post, you need to break the equation into real and imaginary parts, as follows:
f[z_] := 1 + 1/2^z + 1/3^z
FindRoots2D[{Re@f[x + I y], Im@f[x + I y]}, {x, -5, 5}, {y, -5, 5}]
(* {{0.454397, -3.59817}, {0.454397, 3.59817}} *)
FindAllCrossings2Dfinds the roots of a system of two equations on the reals (not complexes). You can break your equation into real and imaginary parts then follow the instructions from the post I linked. – Szabolcs Jun 19 '14 at 14:31